By Mary Fieser
The good revered and ever renowned Fieser and Fieser sequence on reagents for natural synthesis offers concise descriptions, strong structural formulation and chosen examples of purposes. * offers references to new reagents in addition to to reagents incorporated in earlier volumes * hundreds of thousands of entries summary an important info on generic and new reagents, together with practise, makes use of, assets of offer, serious reviews, references and extra * Reagents are thought of in alphabetical order by means of universal utilization names.
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This moment version is the most excellent identify source within the box. It offers a convenient source for navigating the net of named reactions and reagents. Reactions and reagents are indexed alphabetically, through appropriate mechanisms, experimental info (including yields the place available), and references to the first literature.
This publication describes the interesting chemistry of the various sorts of natural compounds of hypervalent iodine. every one bankruptcy bargains with a selected iodine compound or households of compounds which were used as reagents in a plethora of valuable variations. those contain diverse oxidation, resembling with the dear Dess-Martin reagent in addition to with quite a lot of extra reactions.
Synthesis of Carbon-Phosphorus Bonds, moment version is a operating advisor for the laboratory, incorporating classical techniques with the hot advancements of carbon-phosphorus (C-P) bond formation. those advances comprise the instruction of phosphoranes -- in particular within the use of brief oxophosphoranes as intermediates in organophosphorus compound synthesis ñ in addition to the hot techniques in the direction of the training of compounds with fragrant and vinylic C-P bonds.
Additional resources for Fieser's Reagents for Organic Synthesis Volume 1
7. Carbon–heteroatom coupling reactions The direct palladium- or nickel-catalysed reaction of aryl halides (or pseudo-halides) with nucleophilic amines (the Buchwald–Hartwig amination59,60 ) is a highly useful tool for the preparation of aromatic amines. Due to the importance of aromatic amines, especially in medicinal chemistry, the reaction has since 1994 been extensively studied and continuously developed59,60 . Surprisingly, synthetic organic chemists have been slow to accelerate this reaction using microwave ﬂash heating.
2002, 67, 8877–8884. ¨ 42. Ohberg, L. , One-pot three-step solution phase syntheses of thiohydantoins using microwave heating, Synlett, 2001, 1893–1896. 43. G. , A polymer-supported thionating reagent, J. Chem. , Perkin Trans. 1, 2001, 358–361. 44. , Dallinger, D. , High-speed microwave-promoted hetero-diels-alder reactions of 2(1H)-pyrazinones in ionic liquid doped solvents, J. Org. , 2002, 67, 7904–7907. 45. , Larhed, M. , High-speed Heck reactions in ionic liquid with controlled microwave heating, J.
9. , Moberg, C. , Fast, convenient, and efﬁcient molybdenum-catalysed asymmetric allylic alkylation under noninert conditions: an example of microwavepromoted fast chemistry, Angew. , Int. Ed. , 2000, 39, 3596–3598. 10. A. , Enantioselective palladium-catalysed allylic alkylation using E - and Zvinylogous sulfonates, Org. , 1999, 1, 1563–1565. 11. E. , Transition-metal-free Suzuki-type coupling reactions, Angew. , Int. Ed. , 2003, 115, 1445–1447. 12. , Lindeberg, G. , 1996, 37, 8219–8222. 13. E.
Fieser's Reagents for Organic Synthesis Volume 1 by Mary Fieser