By D.D. Eley, Herman Pines, Paul B. Weisz (Eds.)
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Aalsberg, W. , Hoijtink, G. , Makor, E. , and Weijland, W. , J. Chem. SOC. p. 3055 (1959). 34. Kearns, D. , J . Am. 83,2110 (1961). 35. Eastman, J. , Thesis, University of California (Berkeley), 1961; University of California Radiation Laboratory Report UCRL-9722, 1961. 35a. Eastman, J. , Androes, G. , J . Chem. Phya. 36,1197 (1962). 36. Chesnut, D. , and Phillips, W. , J . Chem. Phys. 34,684 (1961). 37. Acker, D. , Harder, R. , Hertler, W. , Melby, L. , Benson, R. , and Mochel, W. , J . Am. Soc.
And Benson, A. , Science 108, 304 (1948). 2. Bassham, J. ” PrenticeHall, Englewood Cliffs, New Jersey, 1967. 3. Bassham, J. , in “Handbuch der Pflanzen-physiologie” (M. ), Vol. V, Part 1, p. 884, Springer, Berlin, 1960. 4. Bassham, J. , and Calvin, M. ” W. A. , New York, 1962. 5. Bassham, J. , J. Chem. Educ. 86, 648 (1969); 38, 161 (1961); Soi. American June (1962). 6. Bassham, J. , Comp. Biochem. Phyeiol. 4, 187 (1962). , Science 135, 879 (1962). 7. van Niel, C. , in “The Microbe’s Contribution to Biology” (A.
3 x lOle x p x exp (-E,,,/RT) molecules cm-2 sec-1 ( p in mm Hg) (18) for a mobile activated complex with only one degree of rotational freedom. Theoretical value ( 18') is in rather good accordance with the rate found experimentally by Sachtler and Pahrenfort* ; however Eley and Lueti6's result is far too high, even for the case of fullest mobility. An explanation of this last discrepancy is not available. The activation energy of the adsorption step is rather high, as it is, for instance, in the case of adsorption on the seminoble metal copper (see Section 111,A, 3).
Advances in Catalysis, Vol. 14 by D.D. Eley, Herman Pines, Paul B. Weisz (Eds.)